Stereochemistry of Mixed Thiolate and Ditertiary Phosphine Cobalt(II) Complexes. Crystal Structures of (SPh)2> and (SPh2)2>

DOI: 10.1039/DT9910003145

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Journal of the Chemical Society, Dalton Transactions p. 3145 - 3148 (1991)

Update date:2022-07-29

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Authors:

Wei, Guowei

Hong, Maochun

Huang, Zhiying

Liu, Hanqin

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Article abstract of DOI:10.1039/DT9910003145

The complexes and were prepared in good yields by treating Co(dppp)Cl2 with NaSPh and elemental selenium in dimethylformamide and by treating CoCl2*6H2O and bdpp in acetonitrile with NaSPh, respectively.The complex crystallizes in the triclinic space group P<*>, with a = 9.665(2), b = 10.075(1), c = 18.288(2) Angstroem, α = 102.41(1), β = 93.89(1), γ = 92.40(1) deg and Z = 2, whereas the complex is monoclinic, space group Cc, with a = 16.374(2), b = 26.033(3), c = 10.873(5) Angstroem, β = 117.49(2) deg and Z = 4.

Full text of DOI:10.1039/DT9910003145

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