Stereochemistry of Mixed Thiolate and Ditertiary Phosphine Cobalt(II) Complexes. Crystal Structures of (SPh)2> and (SPh2)2>

DOI: 10.1039/DT9910003145

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3145 - 3148 (1991)

Update date:2022-07-29

Topics:

Authors:

Wei, Guowei

Hong, Maochun

Huang, Zhiying

Liu, Hanqin

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9910003145

The complexes and were prepared in good yields by treating Co(dppp)Cl2 with NaSPh and elemental selenium in dimethylformamide and by treating CoCl2*6H2O and bdpp in acetonitrile with NaSPh, respectively.The complex crystallizes in the triclinic space group P<*>, with a = 9.665(2), b = 10.075(1), c = 18.288(2) Angstroem, α = 102.41(1), β = 93.89(1), γ = 92.40(1) deg and Z = 2, whereas the complex is monoclinic, space group Cc, with a = 16.374(2), b = 26.033(3), c = 10.873(5) Angstroem, β = 117.49(2) deg and Z = 4.

Full text of DOI:10.1039/DT9910003145

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:{bis(2-diphenylphosphinoethyl)phenylphosphine-κ(3)P,P',P''}bis(phenylthio-κS)cobalt(II)

Cas No:138397-66-7

R&D Labs maybe for 138397-66-7

Xinji City Taida Sinopec Co., Ltd.

Contact:0086-311-85341278

Address:No.6, Nanhua Road,Xinji City Road,Hebei Province,China
Anhui Xinyuan Technology Co.,Ltd

Contact:0086-559-3515800

Address:No.16 Zijin Rd, Circular Economic Zone, Huizhou District, Huangshan Anhui China
Shanghai Zhihua ChemTech Co., Ltd.

Contact:+86-13774313779

Address:Room 817 Suite B 3333 Shenjiang Road
Changzhou Litong Chemical Co., Ltd.

website:http://www.litonchem.com/

Contact:+86-519-86301238

Address:Laoba Rd, Hutang town Changzhou Jiangsu
Shandong Bolode Bio-Technology Co., LTD

Contact:+86-0531-58966870

Address:136 Jingyi Road,Huaiyin District,Jinan,Shandong,China

Relevant to this article

Primary alcohols from terminal olefins: Formal anti-Markovnikov hydration via triple relay catalysis

Doi:10.1126/science.1208685
(2011)
A sulfate-bridged Cu^II complex with 1-D helical-chain structure: Synthesis, structure and magnetic property

Doi:10.1016/j.inoche.2012.03.035
(2012)
A tandem Diels-Alder/Mannich approach to the synthesis of AE and ABE ring analogues of Delphinium alkaloids

Doi:10.1016/j.tet.2012.05.037
(2012)
Synthesis, DNA binding, hemolytic, and anti-cancer assays of curcumin I-based ligands and their ruthenium(III) complexes

Doi:10.1007/s00044-012-0133-8
(2013)
Synthesis of unsymmetrical biaryl ureas from N-carbamoylimidazoles: Kinetics and application

Doi:10.1016/j.tet.2012.05.002
(2012)
Naphthalimide-based fluorescent off/on probes for the detection of thiols

Doi:10.1016/j.tet.2012.04.110
(2012)

Article Doi