Preparation of Activated Imines and Their Condensation with Allylstannanes: Stereoselective Synthesis of 1,2-Amino Alcohols

DOI: 10.1021/jo00281a008

Source and publish data:

Journal of Organic Chemistry p. 4739 - 4741 (1989)

Update date:2022-08-05

Topics:

Authors:

Ciufolini, Marco A.

Spencer, George O.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00281a008

A modified Wadsworth-Emmons reaction affords hitherto inaccessible imines derived from aliphatic aldehydes and aromatic amines.Such highly activated imines condense rapidly and stereoselectively with oxygenated allylstannanes, at -78 deg C, under the infl

Full text of DOI:10.1021/jo00281a008

Products guided by the article

Product name:Benzenamine, N-(cyclohexylmethylene)-, (E)-

Cas No:138469-41-7

R&D Labs maybe for 138469-41-7

Frapp's Chemical (NFTZ) Co.,Ltd

Contact:+86-576-86137892

Address:General Chamber of Commercial Building, 159 Wanchang Middle Road, Wenling, Zhejiang, China
Hangzhou utanpharma Co., Ltd

Contact:86-571-87758773

Address:Room604 ,6F, Block A1-3 Xixi Plaza,No. 588 Wenyi West RD, Hangzhou,310012, China
Zhejiang Kangfeng Chemical Co.,LTD.

Contact:+86-579-86709687

Address:Xueshizhai Industrial Zone, Weishan Town,Dongyang City, Zhejiang Province ,China
Hangzhou Pharma & Chem Co.,Ltd.

Contact:+86-571-87040515

Address:No,139Qingchun Rd
Du-Hope International Group

website:http://www.np-chem.com

Contact:0086-25-52346877

Address:199, Jian Ye Road, Nanjing, China

Relevant to this article

Reaction of Dianions of Acyclic β-Enamino Ketones with Electrophiles. 3. Nitriles: Synthesis of Pyridine and Pyrimidine Derivatives

Doi:10.1021/jo00048a043
(1992)
Cu-catalyzed mild C(sp²)-H functionalization assisted by carboxylic acids en route to hydroxylated arenes

Doi:10.1021/ja4047894
(2013)
Synthesis of Optically Active Arylglycines by Photolysis of Optically Active (β-Hydroxyamino) Carbene-Chromium(0) Complexes

Doi:10.1021/jo00051a044
(1992)
Straightforward preparation of labeled potassium cyanate by ozonation and application to the synthesis of [¹³C] or [¹⁴C] ureidocarboxylic acids

Doi:10.1002/jlcr.3041
(2013)
Synthesis and X-ray structure characterisation of novel pyrazolecarboxamide derivatives

Doi:10.3184/174751913X13633729862156
(2013)
Spatially controlled surface immobilization of nonmodified peptides

Doi:10.1002/anie.201302040
(2013)

Article Doi