Preparation of Activated Imines and Their Condensation with Allylstannanes: Stereoselective Synthesis of 1,2-Amino Alcohols

DOI: 10.1021/jo00281a008

Source and publish data:

Journal of Organic Chemistry p. 4739 - 4741 (1989)

Update date:2022-08-05

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Authors:

Ciufolini, Marco A.

Spencer, George O.

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Article abstract of DOI:10.1021/jo00281a008

A modified Wadsworth-Emmons reaction affords hitherto inaccessible imines derived from aliphatic aldehydes and aromatic amines.Such highly activated imines condense rapidly and stereoselectively with oxygenated allylstannanes, at -78 deg C, under the infl

Full text of DOI:10.1021/jo00281a008

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