Preparation of Activated Imines and Their Condensation with Allylstannanes: Stereoselective Synthesis of 1,2-Amino Alcohols

DOI: 10.1021/jo00281a008

Source and publish data:

Journal of Organic Chemistry p. 4739 - 4741 (1989)

Update date:2022-08-05

Topics:

Authors:

Ciufolini, Marco A.

Spencer, George O.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00281a008

A modified Wadsworth-Emmons reaction affords hitherto inaccessible imines derived from aliphatic aldehydes and aromatic amines.Such highly activated imines condense rapidly and stereoselectively with oxygenated allylstannanes, at -78 deg C, under the infl

Full text of DOI:10.1021/jo00281a008

Products guided by the article

Product name:Benzenamine, N-(cyclohexylmethylene)-, (E)-

Cas No:138469-41-7

R&D Labs maybe for 138469-41-7

Jiaxing Taixin Pharmaceutical Chemical Co., Ltd

Contact:0573-82613601

Address:Chemical Park, Jiaxing, Zhejiang, China
NanJing KaiHeng Chemical CO., LTD.

Contact:+86-25-85768391

Address:RM.1704, D, WANDA PLAZA, NO.110, MIDDLE JIANGDONG ROAD, NANJING, CHINA
Shenzhen ZheYi Chemicals Co.,LTD(Shanghai Branch)

Contact:+86-21-54159691

Address:Room1002,Building No.2, Lane 98 Bixiu Road,Minhang District, Shanghai,China 201100
Xi'an Unique Electronic and Chemical Co., Ltd.

Contact:+86-029-88238008

Address:1703# B BUILDING WEST ELECTRONIC ZONE, XI'AN, CHINA
Shanghai Egoal Chemical Co.,Ltd

Contact:+86-21-50333091

Address:Yangming Garden Square 3,YangGao North Road 1188, Pudong New District, Shanghai

Relevant to this article

Reaction of Dianions of Acyclic β-Enamino Ketones with Electrophiles. 3. Nitriles: Synthesis of Pyridine and Pyrimidine Derivatives

Doi:10.1021/jo00048a043
(1992)
Cu-catalyzed mild C(sp²)-H functionalization assisted by carboxylic acids en route to hydroxylated arenes

Doi:10.1021/ja4047894
(2013)
Synthesis of Optically Active Arylglycines by Photolysis of Optically Active (β-Hydroxyamino) Carbene-Chromium(0) Complexes

Doi:10.1021/jo00051a044
(1992)
Straightforward preparation of labeled potassium cyanate by ozonation and application to the synthesis of [¹³C] or [¹⁴C] ureidocarboxylic acids

Doi:10.1002/jlcr.3041
(2013)
Synthesis and X-ray structure characterisation of novel pyrazolecarboxamide derivatives

Doi:10.3184/174751913X13633729862156
(2013)
Spatially controlled surface immobilization of nonmodified peptides

Doi:10.1002/anie.201302040
(2013)

Article Doi