AN ASYMMETRIC TOTAL SYNTHESIS OF (-)-SUPINIDINE

DOI: 10.1016/S0040-4020(01)88287-9

Source and publish data:

Tetrahedron p. 7635 - 7644 (1991)

Update date:2022-08-03

Topics: Asymmetric synthesis Lewis acid Enantioselective Total synthesis Stereoselective Resolution Chirality Chiral Auxiliary Diastereomer

Authors:

Takahata, Hiroki

Banba, Yasunori

Momose, Takefumi

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Article abstract of DOI:10.1016/S0040-4020(01)88287-9

By starting from the N-alkenylurethane 4, the epoxy urethane ent-5, and the pyrrolidine ent-6 available from the Katsuki-Sharpless kinetic resolution of N-benzyloxycarbonyl-3-hydroxy-1-pentenylamine (2) has been elaborated (-)-supinidine (1). Key Words: K

Full text of DOI:10.1016/S0040-4020(01)88287-9

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