Tetrahedron p. 7635 - 7644 (1991)
Update date:2022-08-03
Topics: Asymmetric synthesis Lewis acid Enantioselective Total synthesis Stereoselective Resolution Chirality Chiral Auxiliary Diastereomer
Takahata, Hiroki
Banba, Yasunori
Momose, Takefumi
By starting from the N-alkenylurethane 4, the epoxy urethane ent-5, and the pyrrolidine ent-6 available from the Katsuki-Sharpless kinetic resolution of N-benzyloxycarbonyl-3-hydroxy-1-pentenylamine (2) has been elaborated (-)-supinidine (1). Key Words: K
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