Daphniphyllum Alkaloids. 12. A Proposed Biosynthesis of the Pentacyclic Skeleton. proto-Daphniphylline

DOI: 10.1021/jo00035a009

Source and publish data:

Journal of Organic Chemistry p. 2554 - 2566 (1992)

Update date:2022-08-04

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Authors:

Heathcock, Clayton H.

Piettre, Serge

Ruggeri, Roger B.

Ragan, John A.

Kath, John C.

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Article abstract of DOI:10.1021/jo00035a009

A biosynthetic proposal for the pentacyclic skeleton of the Daphniphyllum alkaloids is put forth (Scheme I) and various ramifications are examined experimentally. proto-Daphniphylline (11), the putative product of this hypothetical biogenesis, has been pr

Full text of DOI:10.1021/jo00035a009

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