Tetrahedron p. 615 - 620 (1981)
Update date:2022-08-04
Topics: Benzene Reaction 2-Nitropropane
Bonvino, V.
Casini, G.
Ferappi, M.
Cingolani, G. M.
Pietroni, B. R.
Friedel-Crafts reaction of benzylic or tertiary nitro compounds with benzene gave normal alkylation products.Similarly, 2-nitropropane (2-NP) gave cumene (1) which underwent further transformation affording a mixture whose behaviour with time was investigated: results were consistent with oxidative formation of the cumyl carbonium ion (7').
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