Tetrahedron p. 8523 - 8528 (1991)
Update date:2022-08-03
Topics:
Yamamoto, Takayoshi
Suemune, Hiroshi
Sakai, Kiyoshi
The ring transformation of cyclic ketones with a carbonyl function at the side chain under acetalization conditions (BF3/ethylene glycol) was studied.The results suggested that this reaction proceeds via acetal pathway as a major course and hemiacetal pathway as a minor course. cis-Cyclohexane-1,2-diol was found to be more effective than ethylene glycol for this ring transformation. Key words: ring transformation; aldol condensation; acetalization; Grob fragmentation; boron trifluoride.
View MoreContact:+86-021-6989-5597
Address:No.80 Yichuan Rd., Putuo District,Shanghai,P.R.China
Shanghai doly chemical Co.,Ltd
Contact:+86-21-34716221
Address:No.328,WuHe Roard,MinHang,ShangHai China
Sichuan All Solid State Materials Co.,Ltd.
website:http://www.kydmaterials.com
Contact:0833-5603116
Address:Airport road Jiajiang county, Sichuan province,China
Shanghai Hanshare Industry Co.,Ltd.
Contact:86 21 20960688
Address:RM902-903,Building E, Wanda Plaza,No.26,Zhoukang Road, Pudong District, Shanghai, China
Nanjing Chemipioneer Pharma&Tech Co.,Ltd
website:http://www.chemipioneer.com.cn
Contact:+86-25-52685700
Address:Room 305，A Block，Biological-Medicine Building，Business Start-up Center，Xin-ke 1st Road, High-tech development zone，Nanjing city，Jiangsu Province, China
Doi:10.1016/0040-4039(91)80417-5
(1991)Doi:10.1016/S0040-4020(01)86511-X
(1991)Doi:10.1063/1.440721
(1980)Doi:10.1021/jm00083a012
(1992)Doi:10.1016/S0022-328X(00)88863-4
(1968)Doi:10.1246/bcsj.64.3296
(1991)
