FACILE RADICAL DECARBOXYLATIVE ALKYLATION OF HETEROAROMATIC BASES USING CARBOXYLIC ACIDS AND TRIVALENT IODINE COMPOUNDS

DOI: 10.1016/0040-4039(91)80221-Q

Source and publish data:

Tetrahedron Letters p. 6559 - 6562 (1991)

Update date:2022-08-04

Topics:

Authors:

Togo, Hideo

Aoki, Masahiko

Yokoyama, Masataka

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Article abstract of DOI:10.1016/0040-4039(91)80221-Q

Many kinds of heteroaromatic bases were easily alkylated by the reaction of carboxylic acids with benzene or pentafluorobenzene via radical decarboxylative pathways.This system was further applied to the reaction with tetrahydrofurylcarboxylic acid, 1-(2,3,5-tri-O-benzyl)-D-ribofuranosylacetic acid, and 1-(2,3,5-tri-O-benzyl)-D-ribofuranosylcarboxylic acid for the model synthesis of C-nucleosides.

Full text of DOI:10.1016/0040-4039(91)80221-Q

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