Pyranose α-Enones Provide Ready Access to Functionalized trans-Decalins via Bis-Annulated Pyranosides Obtained by Intramolecular Diels-Alder Reactions. A Key Intermediate for Forskolin

DOI: 10.1021/jo00030a005

Source and publish data:

Journal of Organic Chemistry p. 1065 - 1067 (1992)

Update date:2022-08-04

Topics:

Authors:

Tsang, Ray

Fraser-Reid, Bert

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00030a005

Intramolecular Diels-Alder routes for the preparation of bis-annulated pyranosides, as chiral precursors of functionalized trans-decalin rings of terpenoid natural products, have been investigated.

Full text of DOI:10.1021/jo00030a005

Products guided by the article

Product name:[2,2-Dimethyl-4-((2S,3S,4R,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-but-3-ynyloxy]-methyl-diphenyl-silane

Cas No:138723-38-3

R&D Labs maybe for 138723-38-3

Huangshi Meifeng Chemical Co.,ltd.

Contact:+86-714-6516706

Address:1941-4-3#,Hubin Avenue,Huangshi,Hubei,China
Shanghai better-in Medical Technology Co.,LTD.

Contact:+86-21-38921049

Address:Lane 720 zhangjianggaoke cailun road, Pudong, Shanghai, room 513
KindChem Co.,Ltd,

Contact:+86-25-85281586

Address:13F,Bld2#,South of Longpan Road
Guangzhou Probig Fine Chemical Co., Ltd.

Contact:020-86297874

Address:No.2, 1/F, No.20, Hetai Road,Hebian Village, Baiyun District,Guangzhou,China
Shenzhen JYMed Technology Co.,Ltd.

website:http://www.jymedtech.com

Contact:+86-755-26612112

Address:1#8,9/F, Biomedicine innovation Industrial Park, No.14, Jinhui Road, Pingshan Sistrict, Shenzhen, China

Relevant to this article

Doi:10.1039/j39690000944
(1969)
Two-in-One Strategy for the Pd(II)-Catalyzed Tandem C-H Arylation/Decarboxylative Annulation Involved with Cyclic Diaryliodonium Salts

Doi:10.1021/acs.orglett.9b02429
(2019)
Photodissociation of molecular chlorine in xenon matrices

Doi:10.1063/1.461979
(1992)
Redox properties of the 17-electron sandwich (η⁵-C₅H₅)Mo(η⁶-C ₆Ph₆): Electrochemical characterization of the 16 e^- Lewis acid monocation and its PF₆^- adduct

Doi:10.1016/S0022-328X(98)01038-9
(1999)
Unsaturated alkylidyne ligands bearing a terminal isocyanide functionality and intervening ethynylbenzene groups

Doi:10.1016/S0022-328X(98)01045-6
(1999)
Synthesis and X-ray crystal structures of the samarium mono(pentamethylcyclopentadienyl) aryloxide complexes (η-C₅Me₅)Sm(O-2,6-t-Bu₂C₆H ₃)₂(THF) and [(η-C₅Me₅)Sm(O-2,6-i-Pr₂C₆H ₃)₃Li(THF)]. Differences in metathesis chemistry of 2,6-di-iso-propylphenoxide.

Doi:10.1016/S0022-328X(98)01046-8
(1999)

Article Doi