The synthesis and reactions with neutral monodentate ligands of the seven-coordinate complex

DOI: 10.1016/0022-328X(94)88039-5

Source and publish data:

Journal of Organometallic Chemistry p. 139 - 146 (1994)

Update date:2022-08-03

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Authors:

Baker, Paul K.

Kendrick, Dafydd ap

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Article abstract of DOI:10.1016/0022-328X(94)88039-5

The reaction of fac- (prepared in situ) with an equimolar quantity of GeCl4 rapidly affords the molybdenum(II) seven-coordinate complex (1) in quantitative yield.Equimolar quantities of 1 and L (L=PPh3, AsPh3 or SbPh3) react in CH2Cl2 or NCMe to give or , respectively.The reactions of and with a series of neutral and anionic donor ligands are described.Complex 1 reacts with two equivalents of L (L=PPh3, AsPh3, SbPh3 or PPh2Cy) in CH2Cl2 to afford and .Reactions of are also discussed.Key words: Molybdenum; Acetonitrile; Germanium; Monodentate

Full text of DOI:10.1016/0022-328X(94)88039-5

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