The synthesis and reactions with neutral monodentate ligands of the seven-coordinate complex

DOI: 10.1016/0022-328X(94)88039-5

Source and publish data:

Journal of Organometallic Chemistry p. 139 - 146 (1994)

Update date:2022-08-03

Topics:

Authors:

Baker, Paul K.

Kendrick, Dafydd ap

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(94)88039-5

The reaction of fac- (prepared in situ) with an equimolar quantity of GeCl4 rapidly affords the molybdenum(II) seven-coordinate complex (1) in quantitative yield.Equimolar quantities of 1 and L (L=PPh3, AsPh3 or SbPh3) react in CH2Cl2 or NCMe to give or , respectively.The reactions of and with a series of neutral and anionic donor ligands are described.Complex 1 reacts with two equivalents of L (L=PPh3, AsPh3, SbPh3 or PPh2Cy) in CH2Cl2 to afford and .Reactions of are also discussed.Key words: Molybdenum; Acetonitrile; Germanium; Monodentate

Full text of DOI:10.1016/0022-328X(94)88039-5

Products guided by the article

Product name:Molybdenum, bis(acetonitrile)dicarbonylchloro(trichlorogermyl)(triphenylphosphine)-

Cas No:138920-51-1

R&D Labs maybe for 138920-51-1

Foreschem Co., Ltd

Contact:+86-533-3112891

Address:zibo
Jiangsu Taihu New Materials Holding Co., Ltd

Contact:+86-519-86160108

Address:Xueyan Town, Changzhou City, Jiangsu Province, 213169, China
Greenutra Resource Inc

website:http://www.greenutra.cn

Contact:0086-411-39553357

Address:No. 7-1-1802, Huizhi Garden,Ocean Square,Dalian, 116033, China
JIANGXI ZHANGFENG CHEMICAL CO., LTD.

Contact:+86-0799-3413066

Address:Xiyuan village, Xiabu Town, Xiangdong District
Jinan Jiaquan Chemical Co.,Ltd

Contact:+86-531-62318366

Address:Room 502 of Yidonghuayuan No.601 Huaxin Road Licheng District Jinan China

Relevant to this article

Mechanism of Carboxylic Acid-Catalyzed Reduction of Substituted Nitrosobenzenes by 1-Benzyl-3,5-bis(1-pyrrolidinylcarbonyl)-1,4-dihydropyridine in Acetonitrile

Doi:10.1246/bcsj.59.3117
(1986)
DIASTEREOSELECTIVE REDUCTION OF AN α-KETO-ESTER DERIVED FROM (-)-8-PHENYLMENTHOL: A 4-step synthesis of R-Halostachine analogue

Doi:10.1016/S0957-4166(00)82014-5
(1991)
Sequential homogenous catalysis. Catalytic formation of allylic and β-keto silyl ethers from dihydrosilanes and the corresponding alcohols followed by intramolecular hydrosilation

Doi:10.1039/CC9960002561
(1996)
Free fatty acid receptor 1 (FFA1/GPR40) agonists: Mesylpropoxy appendage lowers lipophilicity and improves ADME properties

Doi:10.1021/jm3002026
(2012)
Synthesis, crystal structure, antioxidation and DNA-binding studies of a zinc(II) complex with the bis(N-allylbenzimidazol-2-ylmethyl)aniline

Doi:10.1002/jccs.201100456
(2012)
Heterobifunctional ligands: Practical chemoenzymatic synthesis of a cell adhesive glycopeptide that interacts with both selectins and integrins

Doi:10.1021/jm000295r
(2001)

Article Doi