Sequential homogenous catalysis. Catalytic formation of allylic and β-keto silyl ethers from dihydrosilanes and the corresponding alcohols followed by intramolecular hydrosilation

Article abstract of DOI:10.1039/CC9960002561

The catalyst, [Rh(Ph₂PCH₂CH₂PPh₂)]⁺ engages in a consecutive catalytic sequence where allylic alcohols, β-keto alcohols and α,β-unsaturated aldehydes in the presence of dihydrosilanes are first converted to the corresponding monohydrosilyl ethers, which are then cyclized.

Full text of DOI:10.1039/CC9960002561

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