Journal of the Chemical Society, Dalton Transactions p. 2801 - 2806 (1991)
Update date:2022-08-05
Topics:
Bessel, Carol A.
See, Ronald F.
Jameson, Donald L.
Churchill, Melvyn Rowen
Takeuchi, Kenneth J.
The synthesis, characterization, and crystal structure of trans-a = 14.158(2), c = 14.493(3) Angstroem, and Z = 3.Both the RuII-containing cation and the perchlorate anion (which is disordered) lie on a crystallographic two-fold axis.This represents the first structural characterization of a transition-metal complex which utilizes a member of the family of bis(pyrazolyl)pyridine ligands.In addition, the crystal structure yields evidence that the ligand L may be sterically more suitable for co-ordination to a ruthenium(II) centre than the analogous diphenyl-substituted terpyridine ligand, dpt (6,6''-diphenyl-2,2':6'2''-terpyridine).For both tridentate ligands, the donor nitrogen atoms take up three meridional sites and the phenyl substitutents are directed toward the fourth equatorial co-ordination site; however, due to the large distance between the two phenyl arms of L (relative to the dpt), the former ligand can be utilized in synthesizing the present ruthenium(II) complex whereas the analogous dpt complex cannot readily be prepared.
Luzhou North Chemical Co., Ltd.
Contact:+86-830-2796784；+86-830-2796776
Address:Gaoba, Longmatan District, Luzhou, Sichuan Province
Contact:+86-0512-69209969
Address:Room 317,Lushan Road,Suzhou New District,Jiangsu Province,China.
Shanghai Bocimed Pharmaceutical Co., Ltd.
website:http://www.bocimed.com
Contact:+86-21-68861632
Address:Building 1, Lane 647, Songtao Road, Zhangjiang High-Tech Park, Shanghai
Baoding City Light Industry And Textiles Imp.& Exp. Corp. Chemical Department.
Contact:86-312-3262436
Address:NO.658 CHAOYANG SOUTH STREET,BAODING CITY HEBEI CHINA
Shanghai Mintchem Development ., Ltd
Contact:0086 21 5190 8570
Address:R602,4#,89Nong, Mudan Road Pudong Shanghai China
Doi:10.1016/S0040-4020(01)81932-3
(1991)Doi:10.1007/s10593-012-1013-3
(2012)Doi:10.1016/j.jorganchem.2012.05.042
(2012)Doi:10.1007/s10847-013-0348-4
(2014)Doi:10.1016/0040-4039(91)80568-Q
(1991)Doi:10.1016/0040-4039(91)80573-O
(1991)
