Polyhedral Iridathiaborane Chemistry. Reactions of nido-6-SB9H11 and of (1-) with 5-C5Me5)Cl2>2> to give nido-8,7-Iridathiaundecaboranes. A Nuclear Magnetic Resonance and Structural Study

DOI: 10.1039/DT9910002657

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2657 - 2668 (1991)

Update date:2022-07-29

Topics:

Authors:

Nestor, Karl

Fontaine, Xavier L. R.

Greenwood, Norman N.

Kennedy, John D.

Thornton-Pett, Mark

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9910002657

The reaction of <5-C5Me5)Cl2>2> with nido-6-SB9H11 and a non-nucleophilic base yields <8-(η⁵-C5Me5)-nido-8,7-IrSB9H11> 1, whereas with the (1-) anion it yields <8-(η⁵-C5Me5)-9-Cl-nido-8,7-IrSB9H10> 2, <8-(η⁵-C5Me5)-10-Cl-nido-8,7-IrSB9H10> 3 and <1-(η⁵-C5Me5)-closo-1,2-IrSB9H9> 4.With , Cs yields a compound formulated as -arachno-6-SB9H11> which, on thermolysis, yields 9-(PPh3)-arachno-6-SB9H11.The crystal and molecular structures of Cs and compound 2 have been established by single-crystal X-ray diffraction analysis, and all the iridathiaboranes have been examined in detail by (1)H ad (11)B single and multiple magnetic resonance spectroscopy.

Full text of DOI:10.1039/DT9910002657

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:{exo-9-(Cl-trans-(PPh₃)2-cis-H₂Ir)-arachno-6-SB₉H₁₁}

Cas No:139108-02-4

R&D Labs maybe for 139108-02-4

Beijing Cooperate Pharmaceutical Co.,Ltd

website:http://www.cooperate-pharm.com/

Contact:86-01060279497

Address:No.507,Building 4,Tianhua Street, Biomedicine industrial Base
Guangxi Shanyun Biochemical Science and Technology Co., Ltd

Contact:+86-0772--6828887

Address:#2 Industrial Park of Luzhai County, Liuzhou, Guangxi, China
Shandong Yubin Chemical CO.,LTD

website:http://www.yukaichem.com/en.html

Contact:+86-536-8865336

Address:binhai economic development zone，262737 shangdong，china
Shanghai UCHEM Inc.

Contact:+86-21-56338808

Address:799 Dunhuang Road, Putuo
Beijing Stable Chemcial Co.ltd

Contact:86-10-63785052

Address:A1301 Technological Edifice. No.4 FuFeng Road,FengTai District, Beijing. China

Relevant to this article

Homochiral coordination polymers constructed from aminocarboxylate derivates: Effect of bipyridine on the amidation reaction

Doi:10.1016/j.jssc.2012.04.025
(2012)
Structures of Breynins A and B, Architecturally Complex, Orally Active Hypocholesterolemic Spiroketal Glycosides

Doi:10.1021/jo00045a022
(1992)
Synthesis and Photochromism of Dibenzylviologen Coupled with 5,10,15,20-Tetraphenylporphyrin or Its Metal Complex via a Carbonyloxy Spacer

Doi:10.1246/bcsj.65.301
(1992)
Selective Au-C cleavage in (C^∧N^∧C)Au(III) aryl and alkyl pincer complexes

Doi:10.1021/om300666j
(2012)
Analysis of UDP-D-apiose/UDP-D-xylose synthase-catalyzed conversion of UDP-D-apiose phosphonate to UDP-D-xylose phosphonate: Implications for a retroaldol-aldol mechanism

Doi:10.1021/ja305322x
(2012)
Reactivity of a T-shaped cobalt(i) pincer-complex

Doi:10.1039/d1dt00277e
(2021)

Article Doi