Organic Letters p. 4114 - 4117 (2012)
Update date:2022-08-05
Topics:
Jaschinski, Tobias
Hiersemann, Martin
The first uncatalyzed and [Cu(R-box)L2](SbF6) 2-catalyzed {1,6}-transannular Gosteli-Claisen rearrangement of cyclic 2-alkoxycarbonyl-substituted allyl vinyl ethers to afford medium- and large-sized carbacycles is disclosed.
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