Total, asymmetric synthesis of hexoses and azasugars branched at C(5)

DOI: 10.1016/S0040-4020(01)91030-0

Source and publish data:

Tetrahedron p. 9641 - 9658 (1991)

Update date:2022-07-30

Topics:

Authors:

Wagner, Juergen

Vogel, Pierre

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Article abstract of DOI:10.1016/S0040-4020(01)91030-0

The Diels-Alder adduct (-)-5 (a "naked sugar") of furan to 1-cyanovinyl (1R′)-camphanate was converted into (+)-(1R,5S,6S,7S)-6-exo,7-exo-(isopropylidenedioxy)-2,8-dioxabicyclo[3.2.1] octan-3-one and into (+)-(1R,5S,6S,7S)-7-endo-(benzyloxy)-6-exo- {[(t-b

Full text of DOI:10.1016/S0040-4020(01)91030-0

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Product name:(1RS,5SR,6SR,7RS)-7-endo-(benzyloxy)-4,4-dimethyl-6-exo-<<(t-butyl)dimethylsilyl>oxy>-2,8-dioxabicyclo<3.2.1>octan-3-one

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