Journal of Organic Chemistry p. 1625 - 1630 (1981)
Update date:2022-08-05
Topics:
Bruzik, K.
Stec, W.
The thiono-thiolo rearrangement of 1-3 in different protic acids was studied.On the basis of the product distribution and stereochemistry of the resulting phosphorothiolates, an ion-pair mechanism is postulated.Depending on the acidity of the reaction medium and the substrate concentration, internal ion-pair recombination and/or attack of the unprotonated substrate molecule on the dissociated ion pair have been taken into consideration in this postulate.
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