Regioselective functionalization of the methylene group adjacent to cyclopropyl sulfide via mercury(II)-mediated regioselective ring-opening reaction

DOI: 10.1248/cpb.43.1859

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1859 - 1865 (1995)

Update date:2022-07-31

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Authors:

Takemoto

Ohra Ohra

Yonetoku

Iwata Iwata

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Article abstract of DOI:10.1248/cpb.43.1859

A regioselective bond-cleavage of the cyclopropyl sulfide (2) was performed with mercury(11) salt to supply the homoallyl anion synthon (3) bearing two reactive sites at the α and δ positions. The reaction of 3 with n-Bu₃SnH and l₂ g

Full text of DOI:10.1248/cpb.43.1859

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