Regioselective functionalization of the methylene group adjacent to cyclopropyl sulfide via mercury(II)-mediated regioselective ring-opening reaction

DOI: 10.1248/cpb.43.1859

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1859 - 1865 (1995)

Update date:2022-07-31

Topics:

Authors:

Takemoto

Ohra Ohra

Yonetoku

Iwata Iwata

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1248/cpb.43.1859

A regioselective bond-cleavage of the cyclopropyl sulfide (2) was performed with mercury(11) salt to supply the homoallyl anion synthon (3) bearing two reactive sites at the α and δ positions. The reaction of 3 with n-Bu₃SnH and l₂ g

Full text of DOI:10.1248/cpb.43.1859

NII-Electronic Library Service

Products guided by the article

Product name:3-<(1S,6R)-6-(p-tolylthio)bicyclo<4.1.0>hept-1-yl>propyl acetate

Cas No:139590-74-2

R&D Labs maybe for 139590-74-2

Jinan Trio PharmaTech Co., Ltd

Contact:86-531-88811783；+(0)13153010282

Address:2766 Yingxiu Road, Jinan High-Tech Zone, China
QINGDAO TAOSIGN INTERNATIONAL TRADE CO.,LIMITED

Contact:+86-0532-82683616

Address:RM1402, Doublestar Seacoase 7#, No. 5 Guizhou Road, Qingdao, Shandong, China
Shanghai Balmxy Pharmaceutical Co., Ltd

Contact:0086-21-24206007

Address:Room 402, 15#, No. 909 wangyue Road, shanghai, P. R. China
Synochem Ingredients Corp., Ltd.

Contact:+86-512-5636 2180

Address:Zhangjiagang Free Trade Zone
HANGZHOU TOYOND BIOTECH CO., LTD

Contact:+86-571-86965177

Address:No. 189, Fengqi East Road, Hangzhou, China

Relevant to this article

Recyclable, highly efficient and low cost nano-MgO for amide synthesis under SFRC: A convenient and greener 'NOSE' approach

Doi:10.1016/j.apcata.2013.02.016
(2013)
A Bioorthogonal Small Molecule Selective Polymeric "clickase"

Doi:10.1021/jacs.0c06553
(2020)
Approach to construct polysubstituted 1,2-dihydronaphtho[2,1-b]furans and their aerobic oxidative aromatization

Doi:10.1021/jo300827s
(2012)
1-(2-Mercaptobenzenesulfonyl)-3-hydroxyguanidines - Novel potent antiproliferatives, synthesis and in vitro biological activity

Doi:10.1016/j.ejmech.2012.07.042
(2012)
Rhodium-catalyzed asymmetric cycloisomerization of 1,6-ene-ynamides

Doi:10.1002/adsc.201300148
(2013)
Copper(I)-catalyzed formal carboboration of alkynes: Synthesis of tri- and tetrasubstituted vinylboronates

Doi:10.1021/ja307670k
(2012)

Article Doi