Tetrahedron Letters p. 6557 - 6560 (1990)
Update date:2022-08-03
Topics:
Pattenden, Gerald
Smith, Graham F.
A total synthesis of the all-cis cyclopentanetetrol moiety (19) present in funiculosin (1), featuring the Claisen-Ireland rearrangement (8) -> (9), iodolactonisation (9) -> (10a), and the intramolecular oxygen nucleophile displacement (14) -> (16), as key steps, is described.
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Doi:10.1002/chem.201703687
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(1970)
