Sol-Gel Phase Transition of Switch-Functionalized Cholesterols as Detected by Circular Dichroism

DOI: 10.1246/cl.1992.739

Source and publish data:

Chemistry Letters p. 739 - 742 (1992)

Update date:2022-07-30

Topics:

Authors:

Murata, Kazutaka

Aoki, Masayoshi

Shinkai, Seiji

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1992.739

Cholesterol derivatives containing an azobenzene moiety coupled to C3 of a steroidal moiety showed the reversible sol-gel phase transition in certain organic solvents.Strong ICD spectra appeared in the gel phase, but the ICD disappeared in the sol phase.The sol-gel phase transition which accompanies the drastic ICD spectral change was synchronously induced by light-mediated cis-trans isomerism of the azobenzene moiety.

Full text of DOI:10.1246/cl.1992.739

Products guided by the article

Product name:cis-4-methoxy-4'-((cholesteryloxy)carbonyl)azobenzene

Cas No:139879-16-6

R&D Labs maybe for 139879-16-6

TIANJIN FESTO CHEMICAL CO.,LTD(expird)

Contact:86-22-25814570

Address:No.12th,5th Ave.,TEDA,Tianjin,China
Fiarpharmatech Co., Ltd.(expird)

Contact:13482436141

Address:Room 1138, Building 3, No. 555, Huancheng Road(West), Fenxian District, Shanghai
Ningbo Huajia Chemicals

Contact:+86-574-87065746

Address:10th Floor, No.787 Baizhang East Road,
Pengchen New Material Technology Co., Ltd.

Contact:+86-512-63680537

Address:99.6 km of national road 318, Meiyan Community,Pingwang Town, Wujiang District, Suzhou 215225
lianyungang jinkang pharmaceutical technology co., ltd.

Contact:008651885445517

Address:Jinshan industrial park, Ganyu county, Lianyungang, Jiangsu Province, 222115, China

Relevant to this article

(Arylpiperazinyl)cyclohexylsufonamides: Discovery of α_1a/1d-selective adrenergic receptor antagonists for the treatment of Benign Prostatic Hyperplasia/Lower Urinary Tract Symptoms (BPH/LUTS)

Doi:10.1016/j.bmcl.2007.04.008
(2007)
Stable Simple Enols. 5. Solvent Dependence of the Conformation of the OH Group in 2,2-Dimesitylethenol and Several 1,2,2-Triarylethenols

Doi:10.1021/ja00331a039
(1984)
Doi:10.1021/ja00877a024
(1962)
Pd-catalyzed asymmetric allylic alkylation with nitromethane using a chiral diaminophosphine oxide: (S,R_P)-Ph-DIAPHOX. Enantioselective synthesis of (R)-preclamol and (R)-baclofen

Doi:10.1016/j.tetlet.2006.07.029
(2006)
Stereoselective preparation of a cyclopentane-based NK1 receptor antagonist bearing an unsymmetrically substituted sec-sec ether

Doi:10.1021/jo061268x
(2006)
Doi:10.1139/v62-131
(1962)

Article Doi