σ-Assistance of the C4-C7 bond in the solvolysis of 1-norbornyl triflates

DOI: 10.1016/0040-4039(94)88348-3

Source and publish data:

Tetrahedron Letters p. 1793 - 1796 (1994)

Update date:2022-07-29

Topics:

Authors:

Martinez

Garcia Martinez

Barcina Barcina

Osio Barcina

Herrero Herrero

Rodriguez Herrero

De Dios De Dios

Iglesias De Dios

Vilar Vilar

Teso Vilar

Subramanian

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Article abstract of DOI:10.1016/0040-4039(94)88348-3

The solvolysis of 4,7,7-trimethyl-1-norbornyl triflate (5) proceeds under σ-participation of the C₄-C₇ bond, with formation of the σ bridged cation 22 as intermediate.

Full text of DOI:10.1016/0040-4039(94)88348-3

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