σ-Assistance of the C4-C7 bond in the solvolysis of 1-norbornyl triflates

DOI: 10.1016/0040-4039(94)88348-3

Source and publish data:

Tetrahedron Letters p. 1793 - 1796 (1994)

Update date:2022-07-29

Topics:

Authors:

Martinez

Garcia Martinez

Barcina Barcina

Osio Barcina

Herrero Herrero

Rodriguez Herrero

De Dios De Dios

Iglesias De Dios

Vilar Vilar

Teso Vilar

Subramanian

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(94)88348-3

The solvolysis of 4,7,7-trimethyl-1-norbornyl triflate (5) proceeds under σ-participation of the C₄-C₇ bond, with formation of the σ bridged cation 22 as intermediate.

Full text of DOI:10.1016/0040-4039(94)88348-3

Products guided by the article

Product name:Methanesulfonic acid, trifluoro-, 3,3-dimethyl-2-methylenebicyclo[2.2.1]hept-1-yl ester, (1R)-

Cas No:140147-15-5

R&D Labs maybe for 140147-15-5

jiangsu hualin chemical co.,ltd.

Contact:86-25-87787402

Address:jaingsu,china
Shanghai Kangxin Chemical Co., Ltd

Contact:+86 21 60717227

Address:118,Ganbai Village,Waigang Town,Jiading District,Shanghai
Liaoyang Xinyou Chemical Products Co.,Ltd.

Contact:+86-419-5165433 13604191870

Address:Huishang Road6-1, Hongwei District, Liaoyang, Liaoning, China
Weifang Arylchem Chemical Co., LTD

Contact:86-536-5217866

Address:Development Zone, Shouguang, Shandong Province
Ring Specialty Chemicals Inc.

Contact:+1-416-493-6870

Address:Toronto, Canada

Relevant to this article

SYNTHESIS OF N-METHYLPENTAFLUOROPHENYLPYRIDINIUM SALTS

Doi:10.1007/BF00472291
(1991)
A ¹³C and ¹H NMR spectroscopic investigation of the structure of the iminium ion with a dipolar form in metal complexes of 2-N-substituted N-confused porphyrins

Doi:10.1039/c2dt31426f
(2012)
Structure properties relationships of liquid crystal bent core organic semiconductors based on benzo[2,1-b:3,4-b′]dithiophene-4,5-dione

Doi:10.1039/c2jm34803a
(2012)
Potential nootropic agents, 4-alkoxy-2-(1-piperazinyl)quinazoline derivatives

Doi:10.1248/cpb.39.367
(1991)
Amino acids and peptides. XIII. Synthetic studies on N-terminal tripeptide amide analogs of fibrin α-chain

Doi:10.1248/cpb.39.584
(1991)
Simultaneous Double C²/C³ Functionalization of Quinoline with p-Nitrobenzoyl(phenyl)acetylene. One-Pot Synthesis of 3-(4-Nitrobenzoyl)-2-phenylquinoline

Doi:10.1134/S1070428018120205
(2018)

Article Doi