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Studies towards the synthesis of obtusenyne. Synthesis of the hexahydrooxonin nucleus

DOI: 10.1016/S0040-4039(00)92339-6

Source and publish data:

Tetrahedron Letters p. 671 - 674 (1992)

Update date:2022-09-26

Topics:

Authors:

Curtis, Neil R.Curtis, Neil R.

Holmes, Andrew B.Holmes, Andrew B.

Looney, Mark G.Looney, Mark G.

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Article abstract of DOI:10.1016/S0040-4039(00)92339-6

The advanced intermediate (the 2,3,4,7,8,9-hexahydrooxonin) 3 for the synthesis of the Laurencia oxonane natural product, obtusenyne 1 was prepared in 8 steps from the previously reported lactone 4. The key transformations were the stereoselective enolate

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Full text of DOI:10.1016/S0040-4039(00)92339-6

Products guided by the article

Product name:[(Z)-(2S,3R,8R,9S)-3-Benzyloxy-8-(tert-butyl-diphenyl-silanyloxy)-9-ethyl-2,3,4,7,8,9-hexahydro-oxonin-2-yl]-methanol

Cas No:140170-17-8

140170-17-8

R&D Labs maybe for 140170-17-8

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