Chiral orthoesters in organic synthesis: Novel reagents for the enantioselective acylation of silylenolethers

DOI: 10.1016/S0040-4020(01)90792-6

Source and publish data:

Tetrahedron p. 1299 - 1316 (1992)

Update date:2022-08-06

Topics:

Authors:

Longobardo, Luigi

Mobbili, Giovanna

Tagliavini, Emilio

Trombini, Claudio

Umani-Ronchi, Achille

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Article abstract of DOI:10.1016/S0040-4020(01)90792-6

Dialkyl trans-2-alkoxy-2-alkyl-1,3-dioxolan-4,5-dicarboxylates and the corresponding N,N,N,N-tetramethyl-4,5-diamides have been prepared respectively from dialkyl tartrates or tartaric acid diamides. They smoothly reacted with silylenolethers in the prese

Full text of DOI:10.1016/S0040-4020(01)90792-6

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Product name:dimethyl (4R)-trans-2-methyl-2-(2-oxocyclohexyl)-1,3-dioxolan-4,5-dicarboxylate

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