Synthesis and Reactivity of Phosphonato, Phosphato and Arsonato Complexes of Platinum(II)

DOI: 10.1039/DT9920000851

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 851 - 858 (1992)

Update date:2022-08-02

Topics:

Authors:

Kemmit, Raymond D. W.

Mason, Simon

Fawcett, John

Russell, David R.

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Article abstract of DOI:10.1039/DT9920000851

Treatment of the complexes cis-PtCl2L2> (L = donor ligand) with phenylphosphonic acid, methylphosphonic acid, phenyldihydrophosphate or phenylarsonic acid in the presence of an excess of silver(I) oxide in refluxing dichloromethane yielded the new metallacycles , < formula> or respectively.The X-ray crystal structure of showed the presence of a slightly puckered metallacyclic ring with the phosphoryl oxygen adopting an equatorial position.A decomposition product of the complex in solution was shown, via an X-ray crystal structure determination, to be the diorthometallated complex .

Full text of DOI:10.1039/DT9920000851

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