Bulletin of the Chemical Society of Japan p. 2755 - 2760 (1999)
Update date:2022-08-03
Topics:
Takabayashi, Yutaka
Yusa, Takeshi
Minabe, Masahiro
Kimura, Takao
Tsubota, Motohiro
The liquid crystallinity of the title compounds was studied in order to design a stable liquid crystal used at low temperature. The Schiff base derived from 1- or 3-fluoreneamine scarcely shows liquid crystallinity. The propionyl group is effective for lowering the melting point of the mesophase compared to the acetyl group in a series of the title substances. The liquid crystallinity of the title compounds was compared with that of biphenyl homologues. A mesophase of the title substances was observed over a wider range of temperatures than in the case of biphenyl derivatives in a series of propionyl groups.
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