Synthesis and Redox Properties of Substituted 1,4,2-Dithiazines: X-Ray Crystal Structure of 3-(4-Methoxyphenyl)-5,6-dimethyl-1,4,2-dithiazine

Article abstract of DOI:10.1039/c39920000478

The efficient synthesis of a range of novel 1,4,2-dithiazine derivatives by ring expansion of the corresponding 1,3-dithiolium cations in the presence of iodine and aqueous ammonia is reported; the eight ?-electron 1,4,2-dithiazine ring is folded about th