A highly stereoselective synthesis of axially chiral biaryls. Application to the synthesis of a potential chiral catalyst

DOI: 10.1016/S0040-4039(00)91558-2

Source and publish data:

Tetrahedron Letters p. 853 - 856 (1992)

Update date:2022-08-05

Topics:

Authors:

Meyers Meyers

Meier Meier

Rawson Rawson

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Article abstract of DOI:10.1016/S0040-4039(00)91558-2

Excellent diastereoselectivities (>98.2) have been obtained in the biaryl coupling of 2',6',-disubstituted aryl Grignard reagents 1 with aryl oxazolines 6, conveniently synthesised from the optically pure amino alcohols L-valinol and (S)-t-leucinol.

Full text of DOI:10.1016/S0040-4039(00)91558-2

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Product name:Oxazole, 4-(1,1-dimethylethyl)-4,5-dihydro-2-(2,3,4,5-tetramethoxyphenyl)-, (S)-

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