Enantioselective Synthesis of α-Amino Phosphonic Acids by an Application of Stereoselective Opening of Homochiral Dioxane Acetals with Triethyl Phosphite

DOI: 10.1016/S0957-4166(00)80280-3

Source and publish data:

Tetrahedron Asymmetry p. 377 - 378 (1992)

Update date:2022-08-05

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Authors:

Yokomatsu, Tsutomu

Shibuya, Shiroshi

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Article abstract of DOI:10.1016/S0957-4166(00)80280-3

Stereoselective opening of homochiral acetals (2a-c) with triethyl phosphite was applied to the enantioselective synthesis of phosphono alcohols (1a-c), which were succssefully converted to the α-amino phosphonic acid diethyl esters (6a-c).

Full text of DOI:10.1016/S0957-4166(00)80280-3

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Product name:[(R)-1-((1S,3S)-3-Hydroxy-1-methyl-butoxy)-2-phenyl-ethyl]-phosphonic acid diethyl ester

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