An Enantioselective Synthesis of the Spirotetronate Subunit of Kijanolide

DOI: 10.1021/jo00037a005

Source and publish data:

Journal of Organic Chemistry p. 2987 - 2989 (1992)

Update date:2022-08-04

Topics:

Authors:

Marshall, James A.

Xie, Shiping

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00037a005

The Diels-Alder adduct 11 of α-bromoacrolein and triene 9 was converted to spirotetronate 21 throgh a sequence involving Pummerer rearrangement of the derived sulfoxide 16, oxidation of the resulting aldehyde 17, and Dieckmann cyclization of the diester 1

Full text of DOI:10.1021/jo00037a005

Products guided by the article

Product name:2,4-Hexadien-1-ol, 4-[(phenylmethoxy)methyl]-, (Z,E)-

Cas No:141292-86-6

R&D Labs maybe for 141292-86-6

Suzhou HeChuang Chemical Co.,Ltd.

Contact:+86-512-88800520

Address:No.9 Guanchao Rd,Changshu Advanced Materials Industy Park
Dongguan Albiya Energy Science and Technology Co.,Ltd

Contact:+86-769-22181286

Address:Huanan Industial Park, Dongguan,China
Changsha Kamer Essence and Flavor Co.,Ltd

Contact:86-731-89832270

Address:No.327 Kangnin Road Changsha Bio Information Industry Park, Changsha city, Hunan province
Shandong General Materials Co.,Ltd（Shandong Aoertong Chemical Co., Ltd）

Contact:86-531-88072280

Address:No. 1825 Hualong Road, Licheng District, Jinan, Shandong, China
STAR SYNTHESIS CO.,LIMITED

Contact:+(852) 301-98033

Address:Flat C, 23/F, Lucky Plaza, 315-321 Lockhart Road, Wan Chai, Hong Kong

Relevant to this article

Electronic Ligand Modifications on Cobalt Complexes and Their Application toward the Semi-Hydrogenation of Alkynes and Para-Hydrogenation of Alkenes

Doi:10.1021/acs.organomet.9b00337
(2019)
Highly functionalized tetrahydropyridines are cytotoxic and selective inhibitors of human puromycin sensitive aminopeptidase

Doi:10.1016/j.ejmech.2015.10.026
(2015)
First Enantioselective Synthesis of Surinamensinol B and a Non-Natural Polysphorin Analogue by a Two-Stereocentered Hydrolytic Kinetic Resolution

Doi:10.1002/ejoc.201501009
(2015)
C_sp³-C_sp³ and C _sp³-H bond activation of 1,1-disubstituted cyclopentane

Doi:10.1021/ja309830p
(2012)
Cross-coupling of nonactivated primary and secondary alkyl halides with aryl Grignard reagents catalyzed by chiral iron pincer complexes

Doi:10.1055/s-0034-1380136
(2015)
An efficient entry to highly substituted chiral 2-oxopiperazines from α-amino acids via iodocyclization

Doi:10.1016/j.tet.2012.09.109
(2012)

Article Doi