An Enantioselective Synthesis of the Spirotetronate Subunit of Kijanolide

DOI: 10.1021/jo00037a005

Source and publish data:

Journal of Organic Chemistry p. 2987 - 2989 (1992)

Update date:2022-08-04

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Authors:

Marshall, James A.

Xie, Shiping

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Article abstract of DOI:10.1021/jo00037a005

The Diels-Alder adduct 11 of α-bromoacrolein and triene 9 was converted to spirotetronate 21 throgh a sequence involving Pummerer rearrangement of the derived sulfoxide 16, oxidation of the resulting aldehyde 17, and Dieckmann cyclization of the diester 1

Full text of DOI:10.1021/jo00037a005

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