Access to frame-work of linear triquinanes by intermediate of bicyclo [2.1.0] pentane derivatives. Total synthesis of a triquinane, (±) hirsutene

DOI: 10.1016/S0040-4020(01)88514-8

Source and publish data:

Tetrahedron p. 1911 - 1926 (1992)

Update date:2022-07-29

Topics:

Authors:

Franck-Neumann

Miesch Miesch

Lacroix Lacroix

Metz Metz

Kern Kern

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Article abstract of DOI:10.1016/S0040-4020(01)88514-8

The cycloaddition of enamines with electrophilic gem-dimethylcyclopropenes followed by solvolytic ring cleavage of the 2-amino bicyclo [2.1.0] pentane adducts, leads to gem-dimethylcyclopentene derivatives. These reactions are used as key-sequence for the

Full text of DOI:10.1016/S0040-4020(01)88514-8

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