Asymmetric Synthesis of Ketones by SmI2-Mediated Allylation or Benzylation of Ketenes Followed by Enantioselective Protonation

DOI: 10.1246/cl.1992.551

Source and publish data:

Chemistry Letters p. 551 - 554 (1992)

Update date:2022-08-02

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Authors:

Takeuchi, Seiji

Miyoshi, Norikazu

Ohgo, Yoshiaki

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Article abstract of DOI:10.1246/cl.1992.551

SmI2-mediated allylation or benzylation of alkylarylketenes followed by enantioselective protonation with α,α'-di<(S)-2-hydroxy-2-phenylethyl>-o-xylenedioxide gave the corresponding ketones in 61-91percentee.

Full text of DOI:10.1246/cl.1992.551

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