Stereospecific 1,2-ethyl(phenyl)thio group migration in sugars: Stereocontrolled synthesis of precursors to α- and β-2-deoxyglycosides

DOI: 10.1016/0040-4039(92)88142-R

Source and publish data:

Tetrahedron Letters p. 2063 - 2066 (1992)

Update date:2022-09-26

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Authors:

Zuurmond

Van Der Klein

Van Der Marel

Van Boom

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Article abstract of DOI:10.1016/0040-4039(92)88142-R

lodonium ion (NIS/TfOH, _cat.) assisted glycosylation of a sugar acceptor with properly protected enthyl(phenyl)-2-O-phenoxythiocarbonyl 1-thio-β-D-gluco- or 1-thio-α-D-mannopyranoside donors gives the respective 1,2-trans linked 2′-ethyl(phenyl

Full text of DOI:10.1016/0040-4039(92)88142-R

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Product name:1-O-Phenoxythiocarbonyl 2,3,4,6-tetra-O-acetyl-α/β-D-glucopyranose

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