Stereoselective Syntheses of 2,4:5,6-Di-O-isopropylidene-1-C-phenyl-D-glycero-D-ido-hexitol and 2,4:5,6-Di-O-isopropylidene-1-C-phenyl-D-glycero-D-gulo-hexitol from D-glycero-D-gulo-Heptono-γ-lactone. X-Ray Structure of 1-O-Acetyl-2,4:5,6-di-O-isopropylid

DOI: 10.1039/P19920000887

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 887 - 894 (1992)

Update date:2022-07-30

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Authors:

Shing, Tony K. M.

Tsui, Hon-chung

Zhou, Zhao-hui

Mak, Thomas C. W.

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Article abstract of DOI:10.1039/P19920000887

D-glycero-D-gulo-Heptonolactone has been converted by three consecutive reactions (acetonation, reduction and glycol cleavage reaction) into 2,4:5,6-di-O-isopropylidene-D-glucose which with phenylmagnesium bromide gave preponderantly 2,4:5,6-di-O-isopropy

Full text of DOI:10.1039/P19920000887

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