SYNTHESIS OF (4E,8E,2S,3R,2'R)-N-2'-HYDROXYHEXADECANOYL-1-O-β-D-GLUCOPYRANOSYL-9-METHYL-4,8-SPHINGADIENINE, THE FRUITING-INDUCING CEREBROSIDE IN A BASIDIOMYCETE SCHIZOPHYLLUM COMMUNE

DOI: 10.1016/S0040-4020(01)96633-5

Source and publish data:

Tetrahedron p. 2379 - 2386 (1985)

Update date:2022-07-30

Topics: Synthesis Yield NMR spectroscopy Chromatography Purification Reaction Spectroscopic Analysis

Authors:

Mori, Kenji

Funaki, Yuji

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Article abstract of DOI:10.1016/S0040-4020(01)96633-5

The title compound was synthesized by employing (R)-2-aminohexadecanoic acid, D-glucose and (S)-serine as the chiral sources, and the synthetic sample was found to be chemically and biologically identical with the fruiting-inducing cerebroside isolated fr

Full text of DOI:10.1016/S0040-4020(01)96633-5

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Product name:(4E,8E,2S,3R,2'R)-N-2'-hydroxyhexadecanoyl-1-O-(tetra-O-acetyl-β-D-glucopyranosyl)-3-O-(t-butyldiphenylsilyl)-9-methyl-4,8-sphingadienine

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