A homoleptic (aryl isocyanide)iron(0) dimer. X-ray structure determination of nonakis(phenyl isocyanide)diiron

DOI: 10.1021/om00043a076

Source and publish data:

Organometallics p. 2734 - 2736 (1992)

Update date:2022-08-04

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Authors:

Ruiz, Javier

Riera, Víctor

Vivanco, Marilin

García-Granda, Santiago

Pertierra, Pilar

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Article abstract of DOI:10.1021/om00043a076

Nonakis(phenyl isocyanide)diiron was prepared by sodium amalgam reduction of either cis- or trans-[FeI₂(CNPh)₄]. The new complex was characterized spectroscopically and by single-crystal X-ray analysis. Crystal data: monoclinic, space group P2₁/n, a = 12.692 (5) ?, b = 27.086 (8) ?, c = 15.735 (3) ?, β = 92.90 (2)°, V = 5402 (3) ?³, Z = 4, R = 0.032.

Full text of DOI:10.1021/om00043a076

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