A Novel Stereospecific Rearrangement of 3-Substituted B-Homo 5-Azasteroids to Their A-Nor Analogues. Preparation, Stereochemistry, and Conformational Studies

DOI: 10.1021/jo00041a013

Source and publish data:

Journal of Organic Chemistry p. 4110 - 4121 (1992)

Update date:2022-08-02

Topics:

Authors:

Back, Thomas G.

Chau, Joseph H.-L.

Codding, Penelope W.

Gladstone, Patricia L.

Jones, David H.

et al. et al.

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Article abstract of DOI:10.1021/jo00041a013

The novel 3α- and 3β-hydroxy-B-homo-5-azasteroid lactams 4 and 5 were prepared from testosterone.When the hydroxyl group in these compounds is converted into a leaving group, rearrangement to the corresponding A-nor azasteroids occurs under a variety of c

Full text of DOI:10.1021/jo00041a013

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