The effect of remote oxygens on the ring-opening reactions of oxabicyclic compounds with organolithium reagents. Synthesis of the C21-C27 segment of rifamycin S

DOI: 10.1016/S0040-4039(00)79040-X

Source and publish data:

Tetrahedron Letters p. 2617 - 2620 (1992)

Update date:2022-08-05

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Authors:

Lautens Lautens

Belter Belter

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Article abstract of DOI:10.1016/S0040-4039(00)79040-X

The reactivity of several related oxabicyclo[3.2.1]octenes toward ring-opening was found to depend on the stereochemistry of a remote hydroxyl group. It was also found that attenuation of the reactivity occurred upon protection of the remote alcohol.

Full text of DOI:10.1016/S0040-4039(00)79040-X

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