Formation of Heterobicyclic Compounds through Successive Insertion of Isocyanides into a Palladium-Hydride Bond

DOI: 10.1039/c39920000707

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 707 - 708 (1992)

Update date:2022-09-26

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Authors:

Tanase, Tomoaki

Ohizumi, Tetsuro

Kobayashi, Kimiko

Yamamoto, Yasuhiro

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Article abstract of DOI:10.1039/c39920000707

Reaction of PdCl2(PPh3)2 1 with an excess of H2SiMePh and 2,6-xylyl isocyanide gives *1/2C6H6 (3, R = 2,6-xylyl) and heterobicyclic compound 2,6-(2',6'-xylyl)2-3,7-(N-2',6'-xylylimino)2-4,8-(N-2',6'-xylylamino)2-2,6-diaza-bicyclo<3.3.0>octa-4,8-d

Full text of DOI:10.1039/c39920000707

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