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Formation of Heterobicyclic Compounds through Successive Insertion of Isocyanides into a Palladium-Hydride Bond

DOI: 10.1039/c39920000707

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 707 - 708 (1992)

Update date:2022-09-26

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Authors:

Tanase, TomoakiTanase, Tomoaki

Ohizumi, TetsuroOhizumi, Tetsuro

Kobayashi, KimikoKobayashi, Kimiko

Yamamoto, YasuhiroYamamoto, Yasuhiro

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Article abstract of DOI:10.1039/c39920000707

Reaction of PdCl2(PPh3)2 1 with an excess of H2SiMePh and 2,6-xylyl isocyanide gives *1/2C6H6 (3, R = 2,6-xylyl) and heterobicyclic compound 2,6-(2',6'-xylyl)2-3,7-(N-2',6'-xylylimino)2-4,8-(N-2',6'-xylylamino)2-2,6-diaza-bicyclo<3.3.0>octa-4,8-d

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Product name:Pyrrolo[3,2-b]pyrrol-2(1H)-one, 1,4-bis(2,6-dimethylphenyl)-3,6-bis[(2,6-dimethylphenyl)amino]-5-[(2,6- dimethylphenyl)imino]-4,5-dihydro-, (E)-

Cas No:142095-22-5

142095-22-5

R&D Labs maybe for 142095-22-5

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