The Trifluoromethanesulfonates of Dimethylsilyl Ethers as Intermediates for Silicon Protective Groups

DOI: 10.1007/BF00817591

Source and publish data:

Monatshefte fur Chemie p. 369 - 372 (1992)

Update date:2022-08-04

Topics:

Authors:

Weinzierl, Uwe

Seidel, Wolfgang

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Article abstract of DOI:10.1007/BF00817591

The reaction of mesityldimethylsilyl ethers with CF3SO3H yields selectively mesitylene.The resulting Si-trifluormethanesulfonates were reacted with t-BuLi to give the corresponding t-BuMe2Si-ethers.Keywords: Alcohol protective groups; t-Butyldimethylsilyl ethers; Mesityldimethylsilyl ethers; Trifluormethanesulfonates.

Full text of DOI:10.1007/BF00817591

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