The Trifluoromethanesulfonates of Dimethylsilyl Ethers as Intermediates for Silicon Protective Groups

DOI: 10.1007/BF00817591

Source and publish data:

Monatshefte fur Chemie p. 369 - 372 (1992)

Update date:2022-08-04

Topics:

Authors:

Weinzierl, Uwe

Seidel, Wolfgang

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1007/BF00817591

The reaction of mesityldimethylsilyl ethers with CF3SO3H yields selectively mesitylene.The resulting Si-trifluormethanesulfonates were reacted with t-BuLi to give the corresponding t-BuMe2Si-ethers.Keywords: Alcohol protective groups; t-Butyldimethylsilyl ethers; Mesityldimethylsilyl ethers; Trifluormethanesulfonates.

Full text of DOI:10.1007/BF00817591

Products guided by the article

Product name:3β-Dimethyltrifluormethansulfonylsiloxy-5-androsten-17-on

Cas No:142095-82-7

R&D Labs maybe for 142095-82-7

wuxi huabin bio-tech Co.,Ltd(expird)

Contact:86-0510-85133006

Address:hubin road NO157
HANGZHOU ZHONGCHANG SCIENTIFIC CO.,LTD

Contact:+86-571-88932183

Address:Hangzhou
Huaian Double Win Chemicals Co.,Ltd.

Contact:+86-13511538872

Address:Blk 43,Greenland Century Town,Huaian District, Huaian City,Jiangsu Province,China
waho int'l company

Contact:+86-579-85206992

Address:No 451 chouzhou north road ,room 1106 int'l business center , yiwu ,china
Wuhan Shengmao Corp

website:http://www.shengmaochem.com

Contact:86-27-82853423, 82819281

Address:Rm 202, A Unit Huaqiao Building No. 2, Lihuangpi Road, Wuhan, China

Relevant to this article

Asymmetric organocatalytic allylic alkylation of Reissert compounds: A facile access to chiral 1,1-disubstituted 1,2-dihydroisoquinolines

Doi:10.1039/c2ob27269e
(2013)
Cycloaddition of C,N-Diarylnitrones to 2-Butenolide: Synthesis of 2,3,6,6a-Tetrahydrofuro<3,4-d>isoxazol-4(3aH)-one

Doi:10.1016/0040-4020(92)85009-4
(1992)
Stereoselective Cyclopropanation as a Way to 1-Aminocyclopropane-1-phosphonic Acids: Rationale for Phosphoryl Group Migration

Doi:10.1002/ejoc.201600111
(2016)
A catalytic enantioselective tandem allylation strategy for rapid terpene construction: Application to the synthesis of pumilaside aglycon

Doi:10.1021/ja400506j
(2013)
Photochromism of asymmetrical diarylethenes with a pyrrole unit: Effects of aromatic stabilization energies of aryl rings

Doi:10.1021/ol400188h
(2013)
Antiproliferative potency of novel benzofuran-2-carboxamides on tumour cell lines: Cell death mechanisms and determination of crystal structure

Doi:10.1016/j.ejmech.2012.11.009
(2013)

Article Doi