1,3-Asymmetric Induction in the Reduction of α-Alkyl β-Ketosulfoxides with DIBAL/ZnBr2

DOI: 10.1016/S0040-4039(00)79069-1

Source and publish data:

Tetrahedron Letters p. 2733 - 2736 (1992)

Update date:2022-07-29

Topics:

Authors:

Barros, David

Carreno, M. Carmen

Ruano, Jose L. Garcia

Maestro, M. Carmen

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Article abstract of DOI:10.1016/S0040-4039(00)79069-1

The highly stereoselective reduction of chiral α-alkyl β-ketosulfoxides with DIBAL/ZnBr2 is governed by the configuration at the sulfur (1,3-induction) and not by that of the C-α (1,2-induction) as it has been previously reported.This fact considerably in

Full text of DOI:10.1016/S0040-4039(00)79069-1

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