
Tetrahedron Letters p. 2733 - 2736 (1992)
Update date:2022-07-29
Topics:
Barros, David
Carreno, M. Carmen
Ruano, Jose L. Garcia
Maestro, M. Carmen
The highly stereoselective reduction of chiral α-alkyl β-ketosulfoxides with DIBAL/ZnBr2 is governed by the configuration at the sulfur (1,3-induction) and not by that of the C-α (1,2-induction) as it has been previously reported.This fact considerably in
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