Diastereoselection in the LiA1H4 reduction of severely hindered β-diketones examples of anti-curtin-hammett preequilibrium conditions

DOI: 10.1016/S0040-4020(01)88498-2

Source and publish data:

Tetrahedron p. 3603 - 3610 (1992)

Update date:2022-09-26

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Authors:

Moreno-Manas, Marcial

Galvez, Nicanor

Lloris, Maria E.

Marquet, Jorge

Siani, Antonio C.

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Article abstract of DOI:10.1016/S0040-4020(01)88498-2

LiAlH₄ Reduction of α-adamantyl(and tert-butyl)-β-diketones occur under anti-Curtin-Hammett preequilibrium conditions, each preferred conformer leading to a different stereoisomeric diol, whereas reduction of 3-adamantyl-3-methyl(and ethyl)pent

Full text of DOI:10.1016/S0040-4020(01)88498-2

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