A Difference CD Method for Determining Absolute Stereochemistry of Acyclic 1,2,4-Triols

DOI: 10.1016/0040-4020(95)00329-7

Source and publish data:

Tetrahedron p. 6725 - 6738 (1995)

Update date:2022-08-03

Topics:

Authors:

Mori, Yuji

Furukawa, Hiroshi

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Article abstract of DOI:10.1016/0040-4020(95)00329-7

A general method based on difference circular dichroic (DIF CD) spectroscopy for assigning the absolute configuration of 1,2,4-triol is presented.Four possible stereoisomers of 6-heptene-1,2,4-triol were prepared and served as models to develop the procedure.The sign of the DIF CD Cotton effect is correlated to the absolute configuration of the C2 position.

Full text of DOI:10.1016/0040-4020(95)00329-7

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