
Tetrahedron p. 6725 - 6738 (1995)
Update date:2022-08-03
Topics:
Mori, Yuji
Furukawa, Hiroshi
A general method based on difference circular dichroic (DIF CD) spectroscopy for assigning the absolute configuration of 1,2,4-triol is presented.Four possible stereoisomers of 6-heptene-1,2,4-triol were prepared and served as models to develop the procedure.The sign of the DIF CD Cotton effect is correlated to the absolute configuration of the C2 position.
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