Trifluoromethylation of chiral aldehyde and synthesis of 6-deoxy-6,6,6-trifluorohexoses

DOI: 10.1248/cpb.39.2459

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 2459 - 2461 (1991)

Update date:2022-08-04

Topics:

Authors:

Hanzawa Hanzawa

Uda Uda

Kobayashi

Ishido Ishido

Taguchi Taguchi

Shiro Shiro

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Article abstract of DOI:10.1248/cpb.39.2459

Trifluoromethylation of chiral aldehyde derived from sugar was efficiently carried out by a modification of the reported procedure. The preparation of 6,6,6,-trifluoro-L-daunosamine was also achieved by using (2S,3R)-4,4,4-trifluorobutane-1,2,3-triol derivative.

Full text of DOI:10.1248/cpb.39.2459

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