Tetrahedron Letters p. 2455 - 2458 (1992)
Update date:2022-07-30
Topics:
Mohr, Peter
Z-allylsilanes 1 are epoxidized by V5+/TBHP with high erythro-selectivity (up to 97:3). HF- or TBAFinduced fragmentation leads to syn-l,3-diols 3. Compound 3f can be gtransformed within two steps into a key synthon for the lactone moiety of com
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(1992)