Ring expansion of benzocyclic ketones via transient alkoxyl radicals: The side chain incorporation approach

DOI: 10.1016/S0040-4020(01)88482-9

Source and publish data:

Tetrahedron p. 4027 - 4038 (1992)

Update date:2022-07-30

Topics:

Authors:

Bowman, W. Russell

Westlake, Paul J.

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Article abstract of DOI:10.1016/S0040-4020(01)88482-9

Radical cyclisation onto carbonyl groups followed by β-sission of the resulting alkoxy radicals provides a method for the one-carbon ring expansion of benzocyclic ketones. The radicals are generated by Bu₃SnH reduction of bromomethyl moieties α

Full text of DOI:10.1016/S0040-4020(01)88482-9

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