Mild transformation of telluro and seleno esters into carboxylic acid and esters

Article abstract of DOI:10.1080/00397919208021636

Te-Butyl Telluroesters and Se-Butyl Selenoesters are hydrolyzed to carboxylic acids under very mild conditions by reaction with copper(II) chloride dihydrate. When the reaction is performed in ethanol or methanol, using anhydrous copper(II) chloride a transesterification occurred leading to the oxygenated esters in good yield.

Full text of DOI:10.1080/00397919208021636

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Synthetic Communications: An
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Organic Chemistry
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Mild Transformation of
Telluro and Seleno Esters into
Carboxylic Acid and Esters
Miguel J. Dabdoub a & Luiz H. Viana a
a Departamento de Química, F.F.C.L. , Universidade
de São Paulo , Av. Bandeirantes, 3900, Ribeirão
Preto, SP, Brasil
Published online: 23 Sep 2006.
To cite this article: Miguel J. Dabdoub & Luiz H. Viana (1992) Mild Transformation of
Telluro and Seleno Esters into Carboxylic Acid and Esters, Synthetic Communications:
An International Journal for Rapid Communication of Synthetic Organic Chemistry,
22:11, 1619-1625, DOI: 10.1080/00397919208021636
To link to this article: http://dx.doi.org/10.1080/00397919208021636
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