Journal of Molecular Structure p. 335 - 346 (1992)
Update date:2022-08-05
Topics:
Abdelaoui, O.
Schriver, L.
Schriver, A.
FT-IR spectroscopy has been coupled with the matrix isolation technique to investigate the mechanism of the CBrCl3 photooxidation by ozone at 12 K by UV light.COCl2 is observed as the only primary product and CO as a secondary photolysis product.At 35 K warm up after photolysis generated phosgene complexes with Cl2 and Br2.Identification of these molecular complexes was performed with mixtures of laboratory synthesized phosgene with X (X=Cl2, Br2) trapped in argon matrices.
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