European Journal of Organic Chemistry p. 6177 - 6197 (2019)
Update date:2022-08-15
Topics:
Janke, Sophie
Boldt, Sebastian
Ghazargan, Karapet
Ehlers, Peter
Villinger, Alexander
Langer, Peter
A convenient synthesis of various benzoacridines and benzophenanthridines from readily available dihalogenated quinolines is reported. The synthesis is based on regioselective Suzuki and Sonogashira reactions followed by Br?nsted acid-mediated cycloisomerization. The developed methodology is highly modular and allows the construction of various ring systems and substitution patterns in high yields. The optical and electrochemical properties of selected derivatives were investigated.
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