Synthesis of N-Methoxy and N-H Aziridines from Alkenes

DOI: 10.1016/S0040-4039(00)92062-8

Source and publish data:

Tetrahedron Letters p. 3261 - 3264 (1992)

Update date:2022-07-30

Topics: Synthesis alkenes Aziridines N-H

Authors:

Vedejs, Edwin

Sano, Hiroshi

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Article abstract of DOI:10.1016/S0040-4039(00)92062-8

Electron-rich alkenes are converted into N-methoxyaziridines by treatment with HN(OCH3)2 and trimethylsilyl triflate.Reduction with Li/ammonia affords the N-H aziridines. Key words: Aziridine; N-methoxyaziridine; N-methoxycaprolactam; dimethoxyamine; nitrenium ion

Full text of DOI:10.1016/S0040-4039(00)92062-8

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