Tetrahedron Letters p. 6019 - 6020 (1987)
Update date:2022-07-30
Topics:
Sant, Karey Van
South, Michael S.
α-Enaminoketones are readily accessible through reaction of α-bromoketones with sodium azide followed by an elimination of molecular nitrogen.The reaction is base catalyzed and proceeds under relatively mild conditions.An anionic mechanism is proposed.
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