FORMATION OF α-ENAMINOKETONES FROM α-AZIDOKETONES: AN ELIMINATION OF MOLECULAR NITROGEN FROM α-AZIDOKETONES.

DOI: 10.1016/S0040-4039(00)96852-7

Source and publish data:

Tetrahedron Letters p. 6019 - 6020 (1987)

Update date:2022-07-30

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Authors:

Sant, Karey Van

South, Michael S.

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Article abstract of DOI:10.1016/S0040-4039(00)96852-7

α-Enaminoketones are readily accessible through reaction of α-bromoketones with sodium azide followed by an elimination of molecular nitrogen.The reaction is base catalyzed and proceeds under relatively mild conditions.An anionic mechanism is proposed.

Full text of DOI:10.1016/S0040-4039(00)96852-7

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