FORMATION OF α-ENAMINOKETONES FROM α-AZIDOKETONES: AN ELIMINATION OF MOLECULAR NITROGEN FROM α-AZIDOKETONES.

DOI: 10.1016/S0040-4039(00)96852-7

Source and publish data:

Tetrahedron Letters p. 6019 - 6020 (1987)

Update date:2022-07-30

Topics:

Authors:

Sant, Karey Van

South, Michael S.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)96852-7

α-Enaminoketones are readily accessible through reaction of α-bromoketones with sodium azide followed by an elimination of molecular nitrogen.The reaction is base catalyzed and proceeds under relatively mild conditions.An anionic mechanism is proposed.

Full text of DOI:10.1016/S0040-4039(00)96852-7

Products guided by the article

Product name:(Z)-2-Amino-4,4,4-trifluoro-1-phenyl-but-2-en-1-one

Cas No:115975-52-5

R&D Labs maybe for 115975-52-5

jiangsu senxuan pharmaceutical and chemical co.,ltd

Contact:86-523-87982810

Address:hongqiao industrial zone,taixing,jiangsu china
Huangshan Violet Biological Technology Co., Ltd

Contact:+86-559-2335676

Address:16-201 JinShanYuan,JiangNan New City,TunXi District,HuangShan City,AnHui Province,China
Changzhou Foreign Trade Corp

Contact:+86-519-86623222

Address:29F/D, 99 Yanling West Road, Changzhou, Jiangsu, China
Shandong Zhongcheng Barium Salt Co., Ltd

Contact:+86-15725732638

Address:No.29 baoxi road, hi-tech zone, zibo, shandong
Jiangsu Chiatai Qingjiang Pharmaceutical Co.,Ltd

Contact:+86-517-86283327

Address:9 North Hantai Road, Huaian, China

Relevant to this article

Titanium(IV) halide mediated coupling of alkoxides and alkynes: An efficient and stereoselective route to trisubstituted (E)-alkenyl halides

Doi:10.1021/ol900669t
(2009)
The nature and sequence of the amino acid aglycone strongly modulates the conformation and dynamics effects of Tn antigen's clusters

Doi:10.1002/chem.200801777
(2009)
Scale-up synthesis of a TRPV1 antagonist featuring a facile thiazolo[5,4-d]pyrimidine formation

Doi:10.1021/op1002984
(2011)
CONVERGENT SOLID PHASE PEPTIDE SYNTHESIS. V. SYNTHESIS OF THE 1-4, 32-34, AND 53-59 PROTECTED SEGMENTS OF THE TOXIN II OF ANDROCTONUS AUSTRALIS HECTOR

Doi:10.1016/S0040-4020(01)87802-9
(1987)
Discovery of 2-aminopyridines bearing a pyridone moiety as potent ALK inhibitors to overcome the crizotinib-resistant mutants

Doi:10.1016/j.ejmech.2019.111734
(2019)
Stereoselective synthesis of C-2-methylene and C-2-methyl α-and β-C-glycosides from 2-C-branched glycals: Formal total synthesis of (-)-Brevisamide

Doi:10.1002/ejoc.201403062
(2014)

Article Doi