Dalton Transactions p. 12780 - 12784 (2017)
Update date:2022-08-04
Topics:
Bartalucci, Niccolò
Bortoluzzi, Marco
Funaioli, Tiziana
Marchetti, Fabio
Pampaloni, Guido
Zacchini, Stefano
The full potential of a high valent metal chloride as both a chlorinating and an oxidative agent was explored by allowing WCl6 to react with N-(2,6-diisopropylphenyl) α-diimines, in CH2Cl2 at room temperature. These α-diimines underwent unprecedented conversion to quinoxalinium cations via intramolecular C-N coupling.
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