Allowing the direct interaction of: N -aryl α-diimines with a high valent metal chloride: One-pot WCl6-promoted formation of quinoxalinium salts

DOI: 10.1039/c7dt03226a

Source and publish data:

Dalton Transactions p. 12780 - 12784 (2017)

Update date:2022-08-04

Topics:

Authors:

Bartalucci, Niccolò

Bortoluzzi, Marco

Funaioli, Tiziana

Marchetti, Fabio

Pampaloni, Guido

Zacchini, Stefano

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Article abstract of DOI:10.1039/c7dt03226a

The full potential of a high valent metal chloride as both a chlorinating and an oxidative agent was explored by allowing WCl₆ to react with N-(2,6-diisopropylphenyl) α-diimines, in CH₂Cl₂ at room temperature. These α-diimines underwent unprecedented conversion to quinoxalinium cations via intramolecular C-N coupling.

Full text of DOI:10.1039/c7dt03226a

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