Tetrahedron Letters p. 3439 - 3442 (1992)
Update date:2022-08-05
Topics:
Rawal, Viresh H.
Krishnamurthy, Venkat
Exposure of cyclic acetoxyalkenyl epoxides to a catalytic amount of PhS* initiates a tandem radical induced epoxide fragmentation-H* abstraction-cyclization that results in a net isomerization to bicyclic enolacetates.Key Words: phenylthio radical; enolacetate; radical catalyzed cyclization; epoxide fragmentation
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